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71.
Thanh-Hai Le Yuree Oh Prof. Hyungwoo Kim Prof. Hyeonseok Yoon 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(29):6360-6401
The fascinating properties of single-layer graphene isolated by mechanical exfoliation have inspired extensive research efforts toward two-dimensional (2D) materials. Layered compounds serve as precursors for atomically thin 2D materials (briefly, 2D nanomaterials) owing to their strong intraplane chemical bonding but weak interplane van der Waals interactions. There are newly emerging 2D materials beyond graphene, and it is becoming increasingly important to develop cost-effective, scalable methods for producing 2D nanomaterials with controlled microstructures and properties. The variety of developed synthetic techniques can be categorized into two classes: bottom-up and top-down approaches. Of top-down approaches, the exfoliation of bulk 2D materials into single or few layers is the most common. This review highlights chemical and physical exfoliation methods that allow for the production of 2D nanomaterials in large quantities. In addition, remarkable examples of utilizing exfoliated 2D nanomaterials in energy and environmental applications are introduced. 相似文献
72.
Dr. Lipeng Zhai Dr. Siwen Cui Boli Tong Prof. Weihua Chen Dr. Zijie Wu Prof. Constantinos Soutis Prof. Donglin Jiang Prof. Guangshan Zhu Prof. Liwei Mi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(26):5784-5788
Covalent organic frameworks (COFs) enable precise integration of various organic building blocks into porous skeletons through topology predesign. Here, we report the first example of COFs by integrating electron withdrawing bromine group onto the skeletons for triboelectric nanogenerators (TENG). The resulting framework exhibits high surface area and good crystallinity. Thus, the bromine functionalized COF has more regular aligned π columns and arrays over the skeleton than bare COFs, which in turn significantly enhances charge transport ability. As a result, bromine functionalized COFs showed higher electrical output performance at 5 Hz with a peak value of short circuit current density of 43.6 μA and output voltage of 416 V, which is 2 and 1.3 times higher than those of bare COFs (21.6 μA and 318 V), respectively. These results demonstrated that this strategy for engineering electron withdrawing groups on the skeleton could open a new aspect of COFs for developing TENG devices. 相似文献
73.
Dr. Qingcuomu De Prof. Xinxin Xu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(35):7923-7929
As promising fresh-water purification devices, solar steam generation systems have attracted significant attention recently. However, in practice, the approach often suffers from a poor solar energy conversion efficiency and a low water production rate due to poor material selection and inefficient microscopic structure design. Here, we fabricate an efficient solar steam generation system by “building” polyoxometalate “nano-walls” on rice paper-derived three-dimensional porous carbon paper. In this solar steam generation system, the height of the vertically aligned CoP4Mo6 “nano-walls” range from 100 to 150 nm with thicknesses about 15 to 25 nm. Under 1 sun irradiation (1 sun = 1 kW m−2), the surface temperature increases from 29 to 50 °C in a short time with a solar thermal conversion efficiency achieving 92.8 %. The stability and durability of this solar steam generation system, which withstands fifteen cycle continuous tests, also offer good prospects. Its attractive solar energy conversion performance originates from the intense sunlight absorption and high conversion ability of the CoP4Mo6 “nano-walls”, as well as extremely promising heat localization and water transportation properties of the three-dimensional porous carbon paper. This solar steam generation system, which has produced some inspiring results, is employed for seawater desalination and for purification of water polluted with organic dyes. 相似文献
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Gert-Jan Bekker Mitsugu Araki Kanji Oshima Yasushi Okuno Narutoshi Kamiya 《Journal of computational chemistry》2020,41(17):1606-1615
Multicanonical molecular dynamics based dynamic docking was used to exhaustively search the configurational space of an inhibitor binding to the N-terminal domain of heat-shock protein 90 (Hsp90). The obtained structures at 300 K cover a wide structural ensemble, with the top two clusters ranked by their free energy coinciding with the native binding site. The representative structure of the most stable cluster reproduced the experimental binding configuration, but an interesting conformational change in Hsp90 could be observed. The combined effects of solvation and ligand binding shift the equilibrium from a preferred loop-in conformation in the unbound state to an α-helical one in the bound state for the flexible lid region of Hsp90. Thus, our dynamic docking method is effective at predicting the native binding site while exhaustively sampling a wide configurational space, modulating the protein structure upon binding. 相似文献
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We have used the condensation method to synthesize 2-acetyl-5-methylsemicarbazone ligand. Manganese(II) and Cobalt(II) complexes having formula [ML2]X2 were synthesized where M = Mn(II) and Co(II), L = ligand, X = Cl−, CH3COO−, NO3−, ½SO42−. The characterization data suggests the octahedral geometry for all the synthesized complexes. Tridentate nature of the 2-acetyl-5-methylsemicarbazone ligand was revealed by IR studies. Molar conductance analysis suggested the electrolytic nature of the complexes. The theoretical study includes geometrical optimization, HOMO-LUMO energy gap, energetic parameters and dipole moment. These results also confirmed the tridentate nature of the ligand and the octahedral geometry of complexes. The molecular electrostatic potential (MEP) study suggested the reactive sites for an electrophilic or nucleophilic attack in the ligand. We tested the synthesized compounds for their antifungal and antibacterial action via well diffusion method and found that parent ligand after the coordination with the metal ion showed more effective inhibition against bacteria and fungi. 相似文献
79.
The electronic (energy gap and work function) as well as electrical properties (dipole moment, polarizability, and first hyperpolarizabilities) of the first-row transition metals decorated C24N24 cavernous nitride fullerene were explored using DFT calculations. The transition metals are decorated at N4 cavity of C24N24 fullerene. According to our spin polarized computations, the most stable spin state monotonically increases to sextet for Mn@C24N24 and thereafter dropped off gradually to singlet state for Zn@C24N24 system. The findings demonstrate that transition metals can remarkably decrease the HOMO-LUMO energy gap and work function values up to 63% and 21% of bare C24N24, respectively. As can be seen, when the Sc and Ti metals are located above the N4 cavity of fullerene, systems of enhanced static hyperpolarizabilities (β0) are delivered. These findings might provide an effective strategy to design high performance eletcro-optical materials based on carbon- nitride fullerene. 相似文献
80.
色彩是民族服饰的核心要素,也是民族文化元素的重要组成部分,构建一套兼具科学性与实用性的色彩体系极具挑战性。在传统色彩地理学方法基础上,通过提取主题色和改进的关联规则挖掘方法,获取色彩数据、寻找色彩规则,并对其进行自然色彩体系(NCS)编谱分析,构建了一套苗族服饰色彩体系(Miao’s costume color system,MCCS)。该体系有助于进一步挖掘苗族服饰的配色规律,实现对苗族服饰色彩的数字化保护,为民族服饰色彩传承机理的探索与研究提供新的思路。 相似文献